Clean industrial technology

Zero Emission Flue Gas Treatment

SHU is Green Tech Egypt's patented flue gas treatment system. One water-filled absorption tower replaces the chain of filters, scrubbers and catalysts used in conventional plants, and is designed to meet the strictest European emission limits.

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A revolution in flue gas treatment

Setting a new standard for flue gas emissions

In SHU, flue gases are injected at the bottom of an absorber tank filled with lime water. The water column captures dust, toxic metals and solid particles, while the lime neutralises acid gases. Three things make this effective: a very high contact surface, a small gas/liquid interface volume and a long retention time.

The process is simple and low-cost in both capital and operation. It can be installed as an add-on to existing Waste-to-Energy plants by redirecting flue gases before they reach the chimney, or built into new plants as a complete unit.

50,000×higher contact surface per unit volume than conventional spray scrubbers
99.6%removal efficiency measured on the first prototype by an accredited lab
1 unitone absorption tower instead of filters, carbon injection, scrubber and SCR
~300 Lof water recovered per tonne of waste, instead of water consumed

Why it matters

Cleaner air is the cost driver of Waste-to-Energy

Egypt generates more than 21.7 million tonnes of municipal solid waste every year, and only around 7% reaches an official landfill. Incineration with energy recovery reduces waste volume by about 90% and turns it into heat and power, but only if the flue gases are cleaned properly.

In a conventional Waste-to-Energy plant, flue gas treatment accounts for roughly 30% of total capital and operating costs. Meeting the EU's 2019 Best Available Techniques (BAT) limits typically requires further investment in even more complex systems. SHU was developed to meet current and future limits with a single, simpler unit.

How SHU works

From hot flue gas to clean air in nine steps

An ejector driven by water circulation creates a vacuum that draws the gases in and gives them enough energy to pass through the water head. The tower stays at atmospheric pressure.

SHU process flow diagram: cooling system, ejector, absorption tower, vacuum dewatering, heavy metals mixing tank, clarifier, second dewatering stage, lime mixing tank and clean gas outlet

SHU process flow. Numbers in the diagram match the steps below. Scroll sideways on small screens.

  1. 1

    Cooling

    An air preheater cools flue gases from 150–200 °C to about 70 °C. The recovered hot air can be reused in the plant.

  2. 2

    Ejector

    A high-pressure water ejector mixes gas and liquid and injects the gases at the bottom of the tower.

  3. 3

    Absorption tower

    Lime water at pH 7–8 captures particles, metals and acid gases. A demister keeps droplets in the tower.

  4. 4

    Vacuum dewatering

    The reject stream is dewatered. The solid fly ash leaves cleared of toxic metals.

  5. 5

    Heavy metals tank

    Lime raises the liquid to pH 9–10 so dissolved metals turn into insoluble hydroxides.

  6. 6

    Clarifier

    The metal hydroxides settle out and are separated from the water.

  7. 7

    Toxic reject

    A second dewatering stage collects a small, concentrated toxic reject for secure disposal.

  8. 8

    Lime mixing tank

    Clarified water is dosed with fresh lime from the silo and returned to the tower.

  9. 9

    Clean gas out

    A blower in the chimney releases the cleaned gas, mostly nitrogen, oxygen, CO2 and water vapour.

The science

Gas bubbles in water instead of water droplets in gas

Conventional scrubbers spray droplets of 150–500 µm into a gas stream. SHU reverses this: the tower is filled with liquid and the gas itself becomes the contact surface. Because surface area per unit volume scales with 3/r, this raises the mass transfer rate by about 50,000 times (Fick's first law).

Conventional scrubber

Gas-filled vessel with sprayed droplets of ~50 µm and larger. Low liquid head and short contact time.

1.2 × 10⁻⁴

surface area per unit volume (relative, 3/r)

SHU absorber

Liquid-filled tower with gas dispersed by the ejector, around 0.5 bar of water head and about 20 s retention time.

6

surface area per unit volume (relative, 3/r) — 50,000× higher

What happens to each pollutant

Dust, dioxins, mercury and heavy metals are solid or liquid at 70 °C. They lose their kinetic energy to the water column and cannot escape the tower.

SO2 and HCl dissolve almost instantly and react with lime in under 2 seconds, well within SHU's ~20 s contact time.

NOx is absorbed as nitrous and nitric acids that lime converts into salts.

The optimum operating range is 60–80 °C. Above 80 °C more water evaporates, below 60 °C cooling costs more energy.

Key reactions with lime water

Ca(OH)2 + SO2 → CaSO3 + H2O CaSO3 + ½O2 + 2H2O → CaSO4·2H2O Ca(OH)2 + 2HCl → CaCl2 + 2H2O Ca(OH)2 + 2HF → CaF2 + 2H2O 2NO2 + H2O → HNO3 + HNO2 Ca(OH)2 + 2HNO3 → Ca(NO3)2 + 2H2O

Reactivity with lime: HCl > HF > SO2 > CO2. The resulting salts leave the tower with the reject stream.

Benefits

SHU compared with a traditional system

Traditional flue gas treatment

Baghouse filterElectrostatic precipitatorActivated carbonWet scrubberSCR
  • Several separate cleaning units to build, operate and maintain
  • Existing and new plants need large additional investment to meet BAT 2019 limits
  • Higher energy and chemical use, with 8–10% lime concentration
  • Gases leave at 150–200 °C, so water evaporates and is lost
  • Fly ash carries heavy metals and must go to a hazardous waste site

SHU

One absorption tower
  • Designed to comply with the strictest current EU limits (BAT 2019)
  • Lower capital, maintenance and operating costs, with less energy and fewer chemicals
  • About 1% lime and reject concentration, so a low risk of blockage
  • Recovers 250–300 L of water per tonne of waste (35–40% moisture), reused within the plant
  • Fly ash cleared of heavy metals can be reused in cement or asphalt, or sent to an ordinary landfill. Toxic reject is expected to fall below 10% of a traditional system's

Proven in a prototype

Independent stack measurements on the first SHU unit

The first prototype treated flue gas from a 1 tonne/day waste incinerator, using a 1 m³ absorber with a 0.2 m liquid head and a 0.35 hp ejector pump at pH 8–9. Stack gas was measured by The Expert Company in Cairo, a laboratory accredited by the Egyptian Ministry of Environment, using a calibrated TSI 6203 analyser.

Waste burning in the 1 tonne per day prototype incinerator
Prototype incinerator
Ejector pump and piping injecting flue gases into the absorber
Ejector feeding the absorber
Clear gas leaving the top of the absorber
Clean gas leaving the absorber
ParameterSHU measured
Total particulates (mg/m³)3
CO (mg/m³)2
NOx (mg/m³)1
SO2 (mg/m³)0
Temperature< 90 °C
Overall efficiency99.6%

The supplied SHU presentation also reports HCl at 2 mg/Nm³.

Built in Hurghada

The SHU prototype plant

Green Tech Egypt has built a SHU prototype in Hurghada. It includes every stage of the process: absorption tower, lime preparation, process tanks, exhaust blower and stack, all run from a PLC with a SCADA control screen.

SCADA screen showing incinerator, heat exchanger, absorption tower, pumps, valves, lime screw conveyor and tanks

Automated control

The plant is controlled by a Siemens PLC with a WinCC SCADA screen. Operators see the incinerator, heat exchanger, absorption tower, pumps, valves, lime feed and tank levels on one screen, with live readings for temperature, pressure and level.

Commercial-scale design

Expected performance at commercial scale

Calculated design values from the SHU feasibility study, distinct from the independent measurements on the first prototype.

Pollutant (mg/Nm³)Untreated flue gasSHU expected
Particles (dust)4,000–6,0000
CO–10–50
NOx300–4000–20
SO2450–9000
HCl600–1,5000
Hg0.3–0.50
Cd + Tl1–20
Sb+As+Pb+Cr+Co+Cu+Mn+Ni500
Dioxins and furans (ng TEQ/Nm³)–0

From prototype to plant

Scaling SHU

  1. Tested

    Prototype 1

    1 t/day incinerator, 1 m³ absorber. Independent stack measurements and lab tests on heavy-metal removal.

  2. Next

    Prototype 2

    2 t/day incinerator with cooling from 800 °C to 70 °C, to fix optimal tank dimensions and dosing.

    Flue gas
    600–650 Nm³/h
    Power
    ~60 kWh/day
  3. Design

    Add-on unit

    Retrofit for existing 600 t/day incinerators, placed before the chimney.

    Flue gas
    160,889 Nm³/h
    Power
    ~8,300 kWh/day
  4. Design

    Complete unit

    Fully integrated treatment for new 600 t/day Waste-to-Energy plants.

    Flue gas
    160,889 Nm³/h
    Power
    ~8,500 kWh/day

The prototype was designed for a 20 s retention time. Calculations suggest the required time may be ten times shorter, so the commercial design could be smaller still. Removal of heavy metals from fly ash is supported by first lab tests and will be confirmed with further experiments.

Beyond Waste-to-Energy

One absorber, many industrial uses

The SHU absorption principle can also capture greenhouse gases and be applied to other gas-treatment processes.

Industrial emission controlStacks of factories and power plants
CO2 captureReducing greenhouse gas emissions
Natural gas dehydrationRemoving water vapour
Natural gas sweeteningRemoving acid gases
Ammonia productionProcess gas treatment
Nitric acid manufacturingNOx absorption
Egyptian patentRegistration No. 866/2020
International patentPCT/EG2021/000014
Developed byGreen Tech Egypt with professors, scientists and field experts

Background

Understanding flue gases

Flue gas is a complex mixture created during combustion. It can include water vapour, carbon dioxide, particulates, heavy metals and acidic gases, and results from direct oxidation through incineration or indirect oxidation through gasification and pyrolysis. Many of its components are greenhouse gases.

The US EPA compares gases using Global Warming Potential (GWP): the energy absorbed by one tonne of a gas over a period, usually 100 years, relative to one tonne of CO2. Some gases with a lower GWP and shorter lifetime still contribute significantly because they are present in higher concentrations.

GasGWP (100 yr)Lifetime (yr)2018 (ppmv)
CO215–200408
CH4 methane28121.869
N2O nitrous oxide2651210.331
HFC-2312,4002220.000024*
PFC6,500–9,20010,000–50,000+–
SF623,5003,2000.0000073*

Source: IPCC. *Concentration in 2011.

Part of an integrated Waste-to-Energy system

Discuss SHU for your plant

SHU is part of Green Tech Egypt's ambition to run the cleanest Waste-to-Energy plant in the world. Tell us about your incinerator or industrial process and we will connect you with the right expertise.

Sources: Green Tech Egypt, “SHU Flue Gas Control System – Feasibility study, system description” and SHU presentation (emission limits, benefits).